Showing 1 Result(s)
Diisopropyl azodicarboxylate cas no

Diisopropyl azodicarboxylate cas no

In the below part, please select the country you want us to ship to: Please note that once you've selected a shipping country, all pricing information on our website will be automatically updated to include door-to-door shipping to the country you specified. Diisopropyl azodicarboxylate CAS No.

Signal words: Warning. Remove contact lenses, if present and easy to do. Continue rinsing. All Rights Reserved. Reproduction of any materials from the site is strictly forbidden without permission. Site Use Terms Privacy. Welcome to iChemical. Home Chemical. AI Contact Us. Search all products View all catalogs. Get Quote 0 Buy 0. Formula: C8H14N2O4. Bonaire, Sint Eustatius, and Saba.

South Georgia and the South Sandwich Islands. View all packaging. Available to ship on Feb Available from 1. H Causes skin irritation. H Causes serious eye irritation.

diisopropyl azodicarboxylate cas no

H May cause respiratory irritation. H Suspected of causing cancer.

β˜… Diisopropyl azodicarboxylate - carboxylate esters ..

H Causes damage to organs through prolonged or repeated exposure. H Toxic to aquatic life with long lasting effects. P Avoid release to the environment. P Use personal protective equipment as required. Cas No.Contact Customer Service. CAS Number PubChem Substance ID Reacted with dioxaphosphorinanes and iron catalyst to generate rearranged phosphonium ylide products. Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

Routinely definition adverb

More important for COO: enter a "0" if only two numbers are in front of the letter e. If you find a lot number with a filling-code such as ESβ€” - enter the lot number ES without the filling-code In some cases, a COA may not be available on-line. In many cases a COA can be faxed to you upon submission of this form. One of the most powerful and widely used carboncarbon bond forming reactions in organic synthesis is the Mitsunobu reaction.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others. All Rights Reserved. Reproduction of any materials from the site is strictly forbidden without permission.

Site Use Terms Privacy. USA Home - Diisopropyl azodicarboxylate. Certificate of Analysis COA. Specification Sheet. Similar Products. Show More Description General description Reacted with dioxaphosphorinanes and iron catalyst to generate rearranged phosphonium ylide products.

Safety Information Symbol. Hazard statements. H - H - H - H - H Precautionary statements. Target organs. Personal Protective Equipment. Flash Point F. Flash Point C. How to enter a Lot Number.

Brake drum size chart

View Sample COA. Certificate of Origin COO.

Wetter harz schnee webcam

Bulk Quote-Order Product.Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice. Information on Registered Substances comes from registration dossiers which have been assigned a registration number.

diisopropyl azodicarboxylate cas no

This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice. Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner s of the respective information might violate the rights of the owner.

Diisopropyl azodicarboxylate

EC number: CAS number: Substance Identity Administrative Information. Ecotoxicological Summary Aquatic toxicity Endpoint summary Short-term toxicity to fish Long-term toxicity to fish Short-term toxicity to aquatic invertebrates Long-term toxicity to aquatic invertebrates Toxicity to aquatic algae and cyanobacteria Toxicity to aquatic plants other than algae Toxicity to microorganisms Endocrine disrupter testing in aquatic vertebrates β€” in vivo Toxicity to other aquatic organisms Sediment toxicity Terrestrial toxicity Endpoint summary Toxicity to soil macroorganisms except arthropods Toxicity to terrestrial arthropods Toxicity to terrestrial plants Toxicity to soil microorganisms Toxicity to birds Toxicity to other above-ground organisms Biological effects monitoring Biotransformation and kinetics Additional ecotoxological information.

Inventory Molecular and structural information Related substances.The Brief Profile summarizes the non-confidential data on substances as it is held in the databases of the European Chemicals Agency ECHAincluding data provided by third parties. The Brief Profile is automatically generated; note that it does not currently distinguish between harmonised classification and minimum classification; information requirements under different legislative frameworks may therefore not be fully up to date or complete.

For accuracy reasons, substance manufacturers and imports have the responsibility to consult official sources, e. The information provided in the free-text fields is not published in the Brief Profiles.

The Brief Profile is automatically generated; information requirements under different legislative frameworks may, therefore, not be up-to-date or complete. For accuracy reasons, substance manufacturers and importers are responsible for consulting official sources.

The Brief Profile summarises the non-confidential data on substances as it is held in the databases of the European Chemical Agency ECHAincluding data provided by third parties. Due to the quantity of information and the number of chemicals, the Brief Profile is automatically generated based on the information available and is not manually verified.

For sections such as substance use, chemical properties and the classification and labelling of substances, the quantity and quality of the information is the responsibility of manufacturers and importers. While the Agency tries to aggregate the information on chemicals in the best possible way, ECHA cannot check whether all the information provided by industry is free of errors.

Brief Profiles are updated regularly and new information is added when available. Since the source data can be updated at any time while the Brief Profiles are updated at intervals, a slight delay in the publication of information may occur. Furthermore, updates in the source data may not always result in an update of the Brief Profile.

For example, an update in a section of a dossier that is not displayed in the Brief Profile will not result in an update of the Brief Profile. If you have any comments or suggestions, please contact ECHA using our contact form. All the source data on which the summaries on this page are based, is provided by industry and stored in the ECHA databases. Data from all dossiers registered for the same substance is used in the summarisation and aggregation process, as it is presumed that all data submitted by the registrants is relevant for the substance being registered.

If the test material used is different from the substance being registered an indication will be provided. Please note that the information provided in the free-text fields is not published in the brief profiles. Each endpoint includes three information blocks:. Note: Information presented in this section is generated as part of an automatic process, i.

There are four methods to aggregate and summarise data, depending on the available data and endpoint. An icon is displayed to indicate the type of aggregation and summarisation performed:.

When more than one numerical result is available per endpoint the count is displayed between square brackets.

Mix cumbias 2020 bailables

For other data an order of magnitude logic might apply; e. Due to the number of the substances and the associated information, substance data is processed and aggregated in an automatic process. Therefore, data has to fit the format and aggregation logic that is used for the Brief Profile.

These study results can however be consulted when opening the source data. If only waived data is available for the substance, following justifications for data-waiving can be displayed in the Brief Profile:. Please see the registered dossiers for substance information for the following endpoints:. In addition, information on the type of substance, origin, number and type of registered compositions and other places where the substance is listed are displayed in this section. More information about the EC Inventory can be found here.

These numbers start with 6, 7, 8 or 9. The IUPAC nomenclature is a systematic way of naming chemical substances, both organic and inorganic.Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice. Information on Registered Substances comes from registration dossiers which have been assigned a registration number.

This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice. Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner s of the respective information might violate the rights of the owner.

EC number: CAS number: Substance Identity Administrative Information. Ecotoxicological Summary Aquatic toxicity Endpoint summary Short-term toxicity to fish Long-term toxicity to fish Short-term toxicity to aquatic invertebrates Long-term toxicity to aquatic invertebrates Toxicity to aquatic algae and cyanobacteria Toxicity to aquatic plants other than algae Toxicity to microorganisms Endocrine disrupter testing in aquatic vertebrates β€” in vivo Toxicity to other aquatic organisms Sediment toxicity Terrestrial toxicity Endpoint summary Toxicity to soil macroorganisms except arthropods Toxicity to terrestrial arthropods Toxicity to terrestrial plants Toxicity to soil microorganisms Toxicity to birds Toxicity to other above-ground organisms Biological effects monitoring Biotransformation and kinetics Additional ecotoxological information.

Identification Type of substance Substance identifiers Compositions. Boundary Composition s open all close all Diisopropyl azodicarboxylate.

State Form: liquid Constituent 1. Diisopropyl azodicarboxylate.Diisopropyl azodicarboxylate is diisopropyl ether azodicarbonic acid. It is used as a reagent in the production of many organic compounds. It is often used in reaction Mitsunobu, where it serves as oxidizer of triphenylphosphine to triphenylphosphine oxide. It has also been used to generate Aza-Bayliss-Hillman adducts of acrylates with. It can also serve as selective deprotectant of N-benzyl groups in the presence of other protective groups.

It is sometimes preferably diethyl azodicarboxylate dead, because he no longer could be prevented, and therefore less likely to form hydrazide byproducts. Facebook Twitter.

Oxidation of Alcohols to Carbonyl Compounds with Diisopropyl. Diisopropyl azodicarboxylate. Bis 2. Diisopropyl azodicarboxylate, CAS Number: 83 5.

Diisopropyl Azodicarboxylate. Of diisopropyl azodicarboxylate DIAD under irradiation conditions. Diisopropyl azodicarboxylate is the diisopropyl ester of azodicarboxylic acid.

diisopropyl azodicarboxylate cas no

It is often used in the Mitsunobu reaction, where it serves as an oxidizer of triphenylphosphine to. Product details for Diisopropyl azodicarboxylate.

Diisopropyl azodicarboxylate SynQuest Labs, Inc. In more languages. Copper catalyzed carbonylation of anilines by diisopropyl azodicarboxylate for the synthesis of carbamates. A nitroxyl radical catalyzed oxidation of alcohols using diisopropyl azodicarboxylate DIAD as the terminal oxidant is reported. A variety of. Diisopropyl azodicarboxylate data. The Mitsunobu reaction is an organic reaction that converts an alcohol into a variety of functional groups, such as an ester, using triphenylphosphine and an azodicarboxylate such as diethyl azodicarboxylate DEAD or diisopropyl azodicarboxylate DIAD.

Sigma Aldrich offers a number of Diisopropyl azodicarboxylate products. Supplemental Information. Diisopropyl 1 4 cyanobutanoyl hydrazine 1. Svg is a vector version of this file. It should be used in place of this raster image when not inferior. Read about company. Get contact details and address ID:. Diisopropyl azodicarboxylate pedia. Diisopropyl azodicarboxylate C8H14N2O4 CID structure, chemical names, physical and chemical properties, classification, patents, literature.

Catalogue number: PA 27 Chemical name: Diisopropyl Azodicarboxylate. CAS Number: 83 5.

YLIDE INTRODUCTION ORGRNIC CHEMISTRY CARBONYL COMPOUND BY SUNIL SIR

Category: miscellaneous compounds. Thermal decomposition behavior and decomposition mechanism of diisopropyl azodicarboxylate DIAD were characterized and analyzed by C Diisopropyl azodicarboxylate China Manufacturer Hebei.I agree Our site saves small pieces of text information cookies on your device in order to deliver better content and for statistical purposes.

You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device. Diethyl azodicarboxylate acts as a dienophile used in Diels-Alder reactions. It is used as a reagent in alfa-thiocyanation of enolizable ketones with ammonium thiocyanate and annulation of N-protected imines.

It finds application in Mitsunobu reaction and used in the synthesis of pharmaceuticals like zidovudine and procarbazine. The presence of azo group in it is a Michael acceptor and used for the conversion of beta-ketoesters to the corresponding hydrazine derivatives in presence of copper II catalyst.

Further, it is an efficient dehydrogenating agent, which is involved in the preparation of aldehydes, disulfides from alcohols and thiols respectively. Dehydrogenating agent and aza-dienophile. Oxidizes alcohols to aldehydes, thiols to disulfides and hydrazo to azo groups: J.

Arylhydroxylamines are converted in high yield to nitroso compounds: Chem. Undergoes pericyclic reactions with alkenes and dienes via both ene and Diels-Alder processes.

Paquette, Ed. Secondary and tertiary amines have been dealkylated by reaction with DEAD under mild conditions, followed by acid hydrolysis: J. For reviews, see: Synthesis1 ; Org. For study of the mechanism, see: J.

Details for esterification of - -menthol with 4-nitrobenzoic acid with stereoinversion: Org. For an example of its use to convert a secondary alcohol to an amine by reaction with phthalimide followed by hydrazinolysis, see: Org. For dehydration of Boc-L-serine to the cyclic anhydride 2-oxetanonesee: Org.

Wang, Y. Metal-free, efficient hydrazination of imidazo[1,2-a]pyridine with diethyl azodicarboxylate in neutral media. Xu, N. Palladium-catalyzed direct ortho-ethoxycarbonylation of azobenzenes and azoxybenzenes with diethyl azodicarboxylate. Combustible liquid. Harmful if swallowed. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

diisopropyl azodicarboxylate cas no

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Take off contaminated clothing and wash before reuse.